**Athanase Dupré**'s father was Jean Louis Dupré (1775-1850), a printer, who had married Marie Marguerite Victoire Salmon (1776-?) on 8 February 1796. They had at least seven children, Pierre Louis (born 1797), Marie Anne Victoire (born 1800), Louise Constance Aline (born 1807), the subject of this biography Louis Victoire Athanase (born 1808), Louise Delphine Eugénie (born 1810) and Antoine Ferdinand Palimon (born 1817). A seventh child, Paul, is referred to by Athanase Dupré in a footnote in his book

*Théorie mécanique de la chaleur*Ⓣ where he thanks his "brother Paul" for a helpful suggestion. We have not found a date of birth for Paul Dupré. The Dupré family was Roman Catholic and brought their children up in that faith; Athanase Dupré remained a staunch Catholic throughout his life. He spent his childhood in Cerisiers, in the Yonne department in Burgundy, where he began his education. After completing his school studies at the Collège in Auxerre, the capital of the Yonne department, he entered the École Normale Supérieure in Paris in 1826. He was placed first in his class when he graduated in 1829 having published

*Sur l'explication des phénomènes de la chaleur, de la lumière et de l'électricité*Ⓣ, (1828). After the award of his degree, Dupré was appointed to the Collège Royal in Rennes. He taught mathematics and physics there until 1847, beginning by teaching elementary mathematics and proceeding on to teach physics. He published his first major textbook, namely the two-volume

*Traité élémentaire de physique*Ⓣ (1831), soon after taking up the position at the Collège Royal.

In 1838 Dupré married Louise Euphrasie Rousseau, born in 1804 in Villeneuve-la-Guyard in the Yonne department, and they lived on the rue de Paris in Rennes. They had several children. Édouard Louis Athanase, born 11 July 1839 in Rennes, became professor at the Lycée in Cherbourg and become a Knight of the Légion d'Honneur. Pierre Louis Athanase, born 24 February 1842 in Rennes, became a captain in the navy and an Officer of the Légion d'Honneur. Raphaël Athanase, born 22 September 1843 in Rennes, studied at the École Polytechnique, became director of marine engineering and also became an Officer of the Légion d'Honneur. A fourth son, Paul Louis Athanase Dupré, was born in Rennes, studied at the École Polytechnique and went on to undertake joint work with his father. We say a little more about Paul Louis below.

In 1847 Dupré was appointed to the chair of applied mathematics in the Faculty of Science at Rennes. This Faculty of Science had been set up in 1840 with Felix Dujardin, the professor of zoology, as Dean. The Faculty had twin aims, to train students for their first degree and to popularise science. When Dupré was appointed, the Faculty was housed on the first floor of the north wing in the Rennes City Hall, but new buildings were planned and these were completed in 1855. In 1866 Dupré was appointed dean of the Faculty after the previous dean, the chemist Faustino Malaguti (1802-1878), had been appointed rector of Rennes Academy.

For the first part of his career, from 1826 until 1859, Dupré contributed to a number of different areas in mathematics and physics. He published two papers on number theory in the *Journal de Mathématiques Pures et Appliquées*, the first *Sur le nombre des divisions à effectuer pour obtenir le plus grand commun diviseur entre deux nombres entiers* Ⓣ in 1846 and the second *Sur le nombre de divisions à effectuer pour trouver le plus grand commun diviseur entre deux nombres complexes de la forme a + b*√-1* où a et b sont entiers* Ⓣ in 1848. In the second of these papers Dupré discussed calculating the greatest common divisor of two Gaussian integers. He won an honourable mention for the 1858 Grand Prix of the Academy of Sciences with his paper *Examen d'une proposition de Legendre relative à la Théorie des nombres* Ⓣ on Legendre's theory of numbers. He was awarded one half of the 3000 franc prize.

It looks as if Dupré was somewhat unhappy with the reaction to his work in number theory. He certainly undertook no further work in number theory following the prize announcement and, for the last ten years of his career, he studied the mechanical theory of heat. He published 40 papers on this topic in the Academy of Sciences and made the concepts of thermodynamics well known in France. His work had a major influence on François Jacques Dominique Massieu (1832-1896), a French engineer known for introducing 'free entropy' in 1869, who was a colleague of Dupré's in Rennes during the 1860s. Massieu in turn influenced the work of Willard Gibbs.

During the 1860s Dupré published a series of memoirs on the mechanical theory of heat in the *Annales de Chimie et de Physique*. Dupré's son, Paul Dupré, who became well-known for experimental work in physics particularly involving capillary forces and surface tension in liquids, undertook some joint work with his father which was reported on in some of these memoirs. In his fifth, sixth and seventh memoirs on the mechanical theory of heat Athanase Dupré applied the principles of thermodynamics to capillary action. His son Paul had devised some ingenious experiments to find how surface tension affected capillary action and these played an important role in Dupré's memoirs. In 1866 Athanase and Paul Dupré jointly published the article *On the law of the union of simple substances, and on attractions at small distances*. They begin this paper as follows:-

At a meeting of the Academy of Sciences, held on Monday 19 November 1866, a report on Dupré's sixth memoir was recorded:-The use of weighings in measuring work and molecular forces leads to a precision which has not been hitherto attained. It has become possible to commence the study of attractions at small distances; and there is reason to hope for an early and considerable progress in those branches of the physical sciences which are more directly connected with molecular mechanics.

Some of Dupré's contributions in the 1860s certainly made a very considerable impact. For example, Alexandre Sauzay writes [6]:-M Athanase Dupré addressed to the Academy a sixth memoir on the mechanical theory of heat and molecular mechanics, written in collaboration, for the experimental part, with M Paul Dupré, his son. We admire more and more the perseverance, the fertility and the ability of the great learned professor, and we regret not being able to publish soon what he has offered to the Academy, the statements at least of the many propositions that he has established, with the description of new and often curious experiments with which he confirmed his theories.

Sauzay was not the only one amazed by the result Dupré's. The... to conclude the marvels of the microscope, we cannot do better than mention a rather new discovery which is inserted in a memoir read at the 'Académie des Sciences'(1866), by M Athanase Dupré. Would you know, dear reader, how many molecules there may be in a drop of water? M Dupré has proved that a cube of water, visible only with a powerful microscope, contains more than a hundred and twenty-five thousand millions of molecules. The consequence of this enormous figure is, that in a cube of1^{}/25_{}of an inch, there would be found more than a hundred and twenty-five quintillions.

*Journal of the Franklin Institute*for 1866 reported [5]:-

Here is another example of the impact of Dupré's work: Jacob Bikerman writes in [4] that:-M Athanase Dupré calculates, for the Academy of Sciences of Paris, that a cube of water, having a side equal to one thousandth of a millimetre,(or about six one hundred billionths of a cubic inch,)contains more than125,000,000,000,000,000,000molecules of that valuable compound. If any one doubts this conclusion let him show it to be false by a fair count.

We have mentioned above the influence that Dupré had on Willard Gibbs who was interested in Dupré's work on surface tension as well as many other parts of his work on thermodynamics. Gibbs wrote a paper in 1878, published in the... the ideas of Athanase Dupré ... greatly influenced later scientists. Thus, Lord Rayleigh stated: "we cannot do better than follow the method of Dupré". Dupré popularised the notion of surface tension which he called 'force contractile'.

*Transactions of the Connecticut Academy of Arts and Sciences*, in which he shows his fascination with Dupré's results on surface tension:-

Dupré entered for the Academy of Sciences' Bordin prize for 1866 with the same 'half success' as his entry on number theory. Again he was awarded one half of the prize with an honourable mention. However, he wrote a highly successful advanced textbookAthanase Dupré has determined the surface tensions of solutions of soap by different methods. A statistical method gives for one part of common soap in5000of water a surface tension about one-half as great as for pure water, but if the tension be measured on a jet close to the orifice, the value(for the same solution)is sensibly identical with that of pure water. He explains these different values of the surface tension of the same solution as well as the great effect on the surface tension which a very small quantity of soap or other trifling impurity may produce, by the tendency of the soap or other substance to form a film on the surface of the liquid.

*Théorie mécanique de la chaleur*Ⓣ (1869), which incorporated the memoirs on the topic he had published during the 1860s. Paul Dupré's experimental contributions were highlighted by his father on the title page of

*Théorie mécanique de la chaleur*Ⓣ. Athanase Dupré explains in the Preface why he wrote the treatise and also explained something of his philosophy of how mathematics and physics complement each other:-

The quality of this book was noted by Maxwell in a paper of 20 May 1876, in which he describes Dupré's book as "very ingenious memoirs".Since the end of the year1859I have presented to the Academy a series of memoirs on the 'Théorie mécanique de la chaleur' almost all of which were published in the 'Annales de Chimie et de Physique'. The time seems ripe to correct them, to put them in order, to fill the gaps, and to give my work a form that makes it more useful; this is a work intended to be used for teaching. ... In my opinion, the great utility of mathematical deductions is unquestionable, specific only to deliver in a rigorous manner the consequences of facts or laws provided by observation, or those assumptions that we are sometimes forced to make. We may thus be led to reject these hypotheses or accept such principles after numerous and varied checks leave us no longer in doubt.

Dupré's work on thermodynamics was also taken up by philosophers who saw that it said something fundamental about the universe. For example, Elme Marie Caro, the professor of philosophy in Paris, was influenced by Dupré's work. Helge Kragh explains this philosophical impact in [3]:-

Dupré received relatively little in the way of honours for his mathematical work in view of its importance and its quality. For example he was never elected to the Academy of Sciences. However he did become a Knight of the Légion d'Honneur on 14 August 1863. Paul Dupré continued to make physics experiments after the death of his father. A report on one of these contributions states:-As far as thermodynamics was concerned, Caro relied on the works of Athanase Dupré, dean of the Faculty of Science at the Collège Royal in Rennes and a recognised expert in the new mechanical theory of heat. In1866Dupré had pointed out that although the first law of thermodynamics might seem to lead to an indefinite duration of the present order of nature, this was not the case if the second law was taken into account. 'Thus, in the future, the present order cannot, except for certain modifications, continue for ever. In the past, it is certain that there has been a beginning ... .' Dupré argued that the second law can have operated only in a finite span of time, and Caro adopted his argument. Neither Dupré nor Caro concluded that the world must therefore have been created by God, but it is clear from Caro's exposition that he considered the entropic argument as a welcome support for a divinely created universe.

In1872M Paul Dupré, son of Athanase Dupré, made a disc move through air thick with smoke, being traversed by a ray of sun: he drew the streaks obtained, and found they are more elongated at the back of the disc.

**Article by:** *J J O'Connor* and *E F Robertson*

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